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    The substrate is first dehydrated to 2-keto-3-deoxy-gluconate (KDG) by gluconate dehydratase (CP6013_2550) 114 , followed by phosphorylation to 2-keto-3-deoxy-6-phosphogluconate by 2 …

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    A new chemical route for the preparation of 2-(¹⠸F)fluoro-2-deoxy-D-glucose (2-¹⠸FDG) is discussed using anhydrous (¹⠸F)fluoride produced by the ²°Ne(d,..cap alpha ...

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  • Regioselective Manipulation of GlcNAc Provides Allosamine ...

    2021-3-12 · Palladium-catalyzed oxidation of isopropyl N-acetyl-α-d-glucosamine (GlcNAc) is used to prepare the rare sugars allosamine, lividosamine, and related compounds with unprecedented selectivity. The Passerini reaction applied on 3-keto-GlcNAc provides an entry into branching of the carbon skeleton in this compound.

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    This study investigated the effects of high-intensity ultrasonic processing on a Maillard reaction (MR) model system of D-glucose and L-alanine and its corresponding oil-in-water systems with canola, olive, palm, and coconut oil, respectively. The MR in the water phase was significantly promoted in the olive and canola oil-MR systems with the higher depletion of reactants and the …

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    2019-5-25 · Four deoxy analogs of 2-acetamido-2-deoxy-D-glucose and three deoxy analogs of phenyl 2-acetamido-2-deoxy-β-D-glucoside were synthesized by means of chlorination with sulfuryl chloride and redn. of the chlorides with tri-n-butyltin hydride. The free sugars thus obtained failed to crystallize except for 6-deoxy and 4,6-dideoxy compds.

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  • Tumor Cell Metabolism Imaging | Journal of Nuclear Medicine

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    2.1. Synthesis of glucopyranosyl-conjugated benzyl derivatives. In this study, the designed compounds 8a–i were synthesized through the click reaction ().The key intermediate 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-d-glucose 4 was prepared from commercially available β-d-glucosamine hydrochoride 1, of which the 2-amino group was converted into azido group via reaction with …

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    Scheme 2 outlines the synthetic route taken. Reaction of D-glucose with benzyl alcohol in the presence of acetyl chloride produced benzyl D-glucopyranoside 2 in 86 % yield, which was further modified to produce the 4,6 benzylidiene derivative 3 in 84 % yield, by reaction with benzaldehyde dimethylacetyl and a catalytic amount of (+)-camphor-10-sulfonic acid.

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    2021-4-20 · Glucose Transport. The transporters regulating the uptake of glucose belong to the GLUT family 17 18 19 and constitute a system of stereospecific and saturable transport/countertransport. The isoform that is predominantly expressed at the surface of adult cardiomyocytes is GLUT 4, the insulin-sensitive transporter also found in adipose tissue. 17 In …

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    Carbohydrates are the most abundant organic compounds in the plant world. They act as storehouses of chemical energy (glucose, starch, glycogen); are components of supportive structures in plants (cellulose), crustacean shells (chitin), and

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    For determinations of cytotoxicities of glycolytic inhibitors 2-deoxy-d-glucose (2-DG, Sangon Biotech, Shanghai, China) and dichloroacetate (DCA, Sigma-Aldrich, St. Louis, MO), cells were separately treated in a proper concentration range. 2-DG and antileukemic agent arabinofuranosyl cytidine (Ara-C, Pfizer, New York, NY) were used together to ...

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    2013-11-25 · To characterize the mechanisms involved in glucose transport, in the filamentous fungus Aspergillus nidulans, we have identified four glucose transporter encoding genes hxtB-E. We evaluated the ability of hxtB-E to functionally complement the Saccharomyces cerevisiae EBY.VW4000 strain that is unable to grow on glucose, fructose, mannose or galactose as single …

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    Radiohalogen incorporation into organic systems Radiohalogen incorporation into organic systems Bolton, R. 2002-05-01 00:00:00 R. Bolton* Department of Chemistry, School of Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH, UK Summary This Review reports the more recent applications of radiohalogen labelling in organic compounds.

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    Since 2012, d-glucose has been explored as a safe CEST MRI contrast agent for detecting breast tumors and brain tumors in murine models. Studies showed that d-glucose can generate a broad, strong CEST contrast between 0.8–2.2 ppm (peak position ~1.2–1.3 ppm) and a weak signal at around 2.8 ppm (Figure 3B).

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  • Mitochondria in cancer - Cell Stress

    Mitochondria in cancer – The rediscovery and reinterpretation of the Warburg effect in the year 2000 occulted for almost a decade the key functions exerted by mitochondria in cancer cells. Until recent times, the scientific community indeed focused on constitutive glycolysis as a hallmark of cancer cells, which it is not, largely ignoring the contribution of mitochondria to the malignancy …

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  • Comprehensive studies of organic synthesis by utilizing ...

    2019-5-17 · Instructions for use Title Comprehensive studies of organic synthesis by utilizing chemical features of natural products Author(s) ZETRYANA PUTERI TACHRIM Citation 北海道大学. 博士(農学) 甲第13596号 Issue Date 2019-03-25 DOI 10.14943/doctoral.k13596 Doc ...

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  • (PDF) Introduction to Organic and Biochemistry | Phương ...

    Carbohydrates are the most abundant organic compounds in the plant world. They act as storehouses of chemical energy (glucose, starch, glycogen); are components of supportive structures in plants (cellulose), crustacean shells (chitin), and

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