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    First published on 30th October 2017. The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry and academia to develop of chlorine-free methodologies focused on the use of CO 2 and CO 2-based compounds as feedstocks, promoters and reaction media.In this scenario, dialkyl carbonates (DACs) and in particular dimethyl carbonate (DMC) occupy a privileged position ...

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    The [4+2] cycloaddition between pyrroles and dienophiles has been shown to be a general method for the synthesis of 7-azabicyclo[2.2.1]hepta-2,5-diene and 7-aza­bicyclo[2.2.1]hept-2-ene derivatives. However, pyrrole is a poor diene for the [4+2] cycloaddition and usually …

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